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1 article(s) from Pecher, Lisa

Dispersion-mediated steering of organic adsorbates on a precovered silicon surface

Lisa Pecher,
Sebastian Schmidt and
Ralf Tonner

Beilstein J. Org. Chem. 2018, 14, 2715–2721, doi:10.3762/bjoc.14.249

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Figure 1: Adsorption energy profile of a direct adsorption (black, e.g., cyclooctyne/Si(001)) in comparison w...

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Scheme 1: The reaction of cyclooctyne (1) with a Si(001) surface dimer, yielding a [2 + 2] cycloadduct 2.

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Figure 2: Optimized (PBE-D3/PAW) structure of two molecules of 1 on Si(001) on neighbouring surface dimers (3...

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Figure 3: Energy profile of the adsorption pathway depicted in Scheme 1 on the clean and precovered Si(001) surface c...

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Figure 4: Si(001) Surface precovered with one adsorbate 1 and unit cell used in the PES scans (orientation of...

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Figure 5: Frozen PES scans of 1 along path indicated in Figure 4 (C₂ axis parallel to z, C≡C parallel to y, Δz(Si_up–C...

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Published 26 Oct 2018

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